Description
The CATATEST is a laboratory-scale catalytic testing system designed to evaluate the performance of heterogeneous catalysts under controlled reaction conditions. The system typically consists of a continuous-flow fixed-bed catalytic reactor where reactant gases or liquids pass through a packed bed containing the catalyst. The CATATEST unit allows precise control of temperature, pressure, flow rate, and reactant composition, enabling researchers to study catalyst activity, selectivity, and stability during chemical reactions. Analytical instruments connected to the outlet stream are used to measure product distribution and conversion rates. This setup is commonly used in catalysis research, reaction engineering, and process development to simulate industrial catalytic processes on a small scale while maintaining reliable and reproducible experimental conditions.
Reactions Investigated in the CATATEST System
The CATATEST unit is designed to evaluate catalyst performance for several important industrial catalytic processes. In this system, seven representative reactions are studied using a continuous-flow fixed-bed catalytic reactor in order to analyze catalyst activity, selectivity, and stability under controlled operating conditions.
The main reactions investigated include:
Hydrogenation, Hydroprocessing, and Hydrocracking
These refining processes involve the reaction of hydrocarbons with hydrogen to remove impurities such as sulfur or nitrogen, saturate unsaturated compounds, and break large hydrocarbon molecules into smaller, more valuable fuels.
Methanol Synthesis
Methanol is produced from synthesis gas (a mixture of CO, CO₂, and H₂) over a copper-based catalyst according to reactions such as:
CO + 2H₂ → CH₃OH
Ammonia Synthesis
Ammonia synthesis (Haber–Bosch process) combines nitrogen and hydrogen to produce ammonia:
N₂ + 3H₂ ⇌ 2NH₃
Ammonia Decomposition
Ammonia decomposition is a catalytic reaction in which ammonia breaks down into hydrogen and nitrogen:
2NH₃ ⇌ N₂ + 3H₂
Methane Reforming (Steam and CO₂ Reforming)
Methane reforming processes convert methane into synthesis gas (a mixture of hydrogen and carbon monoxide) using catalytic reactions. Two main reforming pathways can be studied:
Steam Methane Reforming (SMR), where methane reacts with steam over nickel-based catalysts:
CH₄ + H₂O → CO + 3H₂
CO₂ Reforming (Dry Reforming of Methane), where methane reacts with carbon dioxide to produce synthesis gas:
CH₄ + CO₂ → 2CO + 2H₂
Fischer–Tropsch Synthesis
This catalytic process converts synthesis gas (CO and H₂) into long-chain hydrocarbons that can be used as synthetic fuels.
Methanation
Methanation converts carbon oxides and hydrogen into methane, often used for gas purification or synthetic natural gas production:
CO + 3H₂ → CH₄ + H₂O
These reactions represent key industrial catalytic transformations in petrochemical processing, fuel production, and hydrogen-related technologies, making the CATATEST system a valuable tool for catalyst testing and reaction engineering studies.
Features
Operating Conditions
Type I reactor:
Catalyst capacity: 10 cm³
Reactor volume: 30 cm³
Maximum pressure: 10 barg
Maximum temperature: 850 °C
Contruction material: Incoloy 800 H
Type II reactor:
Catalyst capacity: 15 cm³
Reactor volume: 40 cm³
Maximum pressure: 200 barg
Maximum temperature: 550 °C
Contruction material: SS 316
Feed Systems
Gas feed lines: up to 6 mass flow controllers ( N₂ , H₂, CO , CO₂, CH₄ , NH₃, Air ...)
Liquid feed lines: up to 2 HPLC pumps, controlled by Coriolis mass flow controllers
Heated liquid lines
Liquid vaporizer
Static gas mixer
Reaction Section
Pre-heater
Continuous flow Fixed-bed reactor
Down-flow, isothermal operation
3-zone split-tube conduction furnace (50-550°C)
3-zone split-tube radiation furnace (400-900°C)
Product Recovery
Automated back-pressure regulator
Gas-liquid separator with minimal hold-up
Wax trap
Heated effluent lines
3 selectable liquid sampling vessels
Coriolis mass flow meter for liquid measurement
Coriolis mass flow meter for gas counting
GC connections
Automation, Control & Data Management
Fully automated operation via PLC-based control system
User-friendly HMI / SCADA software for:
Real-time monitoring of temperature, pressure, and flow rates
Alarm management and safety interlocks
Trend visualization and historical data logging
Data export for analysis (Excel compatible)
Standalone workstation connected via Ethernet
Safety
Fully enclosed configuration with polycarbonate panels
Gas detector interfacing
Benefits
* Accurate Catalyst Evaluation: CATATEST allows precise measurement of catalyst activity, selectivity, and stability under controlled reaction conditions.
* Simulation of Industrial Processes: The system reproduces conditions similar to those used in industrial catalytic reactors, enabling realistic testing of catalysts.
* Wide Range of Reactions: It can study multiple catalytic processes such as hydrogenation, reforming, methanol synthesis, ammonia reactions, Fischer–Tropsch synthesis, and methanation.
* Precise Control of Operating Parameters: CATATEST provides accurate control of temperature, pressure, gas composition, and flow rates, ensuring reproducible experiments.
* Continuous-Flow Operation: The continuous-flow fixed-bed reactor allows steady-state operation, which is essential for reliable catalytic performance analysis.
* Small Catalyst Requirement: Only small quantities of catalyst are required, making it cost-effective for research and catalyst screening.
* Integration with Analytical Systems: The outlet stream can be directly connected to analytical instruments (e.g., gas chromatography) to monitor product composition and conversion in real time.