Description
The CTV system is a laboratory-scale catalytic testing system designed to evaluate the performance of heterogeneous catalysts under controlled reaction conditions. The system typically consists of a continuous-flow fixed-bed catalytic reactor where reactant gases or liquids pass through a packed bed containing the catalyst. The CTV unit allows precise control of temperature, pressure, flow rate, and reactant composition, enabling researchers to study catalyst activity, selectivity, and stability during chemical reactions. Analytical instruments connected to the outlet stream are used to measure product distribution and conversion rates. This setup is commonly used in catalysis research, reaction engineering, and process development to simulate industrial catalytic processes on a lab scale while maintaining reliable and reproducible experimental conditions.
Reactions Investigated in the CTV System
The CTV unit is designed to evaluate catalyst performance for several important industrial catalytic processes. In this system, seven representative reactions are studied using a continuous-flow fixed-bed catalytic reactor in order to analyze catalyst activity, selectivity, and stability under controlled operating conditions.
The main reactions investigated include:
Hydrogenation, Hydroprocessing, and Hydrocracking
These refining processes involve the reaction of hydrocarbons with hydrogen to remove impurities such as sulfur or nitrogen, saturate unsaturated compounds, and break large hydrocarbon molecules into smaller, more valuable fuels.
Methanol Synthesis
Methanol is produced from synthesis gas (a mixture of CO, CO₂, and H₂) over a copper-based catalyst according to reactions such as:
CO + 2H₂ → CH₃OH
Ammonia Synthesis
Ammonia synthesis (Haber–Bosch process) combines nitrogen and hydrogen to produce ammonia:
N₂ + 3H₂ ⇌ 2NH₃
Ammonia Decomposition
Ammonia decomposition is a catalytic reaction in which ammonia breaks down into hydrogen and nitrogen:
2NH₃ ⇌ N₂ + 3H₂
Methane Reforming (Steam and CO₂ Reforming)
Methane reforming processes convert methane into synthesis gas (a mixture of hydrogen and carbon monoxide) using catalytic reactions. Two main reforming pathways can be studied:
Steam Methane Reforming (SMR), where methane reacts with steam over nickel-based catalysts:
CH₄ + H₂O → CO + 3H₂
CO₂ Reforming (Dry Reforming of Methane), where methane reacts with carbon dioxide to produce synthesis gas:
CH₄ + CO₂ → 2CO + 2H₂
Fischer–Tropsch Synthesis
This catalytic process converts synthesis gas (CO and H₂) into long-chain hydrocarbons that can be used as synthetic fuels.
Methanation
Methanation converts carbon oxides and hydrogen into methane, often used for gas purification or synthetic natural gas production:
CO + 3H₂ → CH₄ + H₂O
These reactions represent key industrial catalytic transformations in petrochemical processing, fuel production, and hydrogen-related technologies, making the CTV system a valuable tool for catalyst testing and reaction engineering studies.
Features
Operating Conditions
Catalyst capacity: up to 150 cm³
Maximum pressure: up to 200 barg
Maximum temperature: up to 550°C
Reactor volume: 500 cm³ (other upon request)
Contruction material: SS316, Incoloy 800 H, HC276
Feed Systems
Gas feed lines – Multiple gas lines with mass flow controllers (N₂, H₂, CO, CO₂, CH₄, NH₃, others upon request).
Liquid feed lines – HPLC pumps with Coriolis mass flow control, additional lines available upon request.
Heated liquid lines
Static gas mixer
Reaction Section
Pre-heater
Continuous flow Fixed-bed reactor
Down-flow, up-flow isothermal operation
5 or 7-zone split-tube furnace with ±1 °C axial uniformity
Product Recovery
Automated back-pressure regulator
Gas-liquid separator with minimal hold-up
Wax trap
Heated effluent lines
Selectable liquid sampling vessels
Coriolis mass flow meter for liquid measurement
Coriolis mass flow meter for gas counting
GC connections
Automation, Control & Data Management
Fully automated operation via PLC-based control system
User-friendly HMI / SCADA software for:
Real-time monitoring of temperature, pressure, and flow rates
Alarm management and safety interlocks
Trend visualization and historical data logging
Data export for analysis (Excel compatible)
Standalone workstation connected via Ethernet
Benefits
* Accurate Catalyst Evaluation: The CTV allows precise measurement of catalyst activity, selectivity, and stability under controlled reaction conditions.
* Simulation of Industrial Processes: The system reproduces conditions similar to those used in industrial catalytic reactors, enabling realistic testing of catalysts.
* Wide Range of Reactions: It can study multiple catalytic processes such as hydrogenation, reforming, methanol synthesis, ammonia reactions, Fischer–Tropsch synthesis, methanation and others.
* Precise Control of Operating Parameters: The CTV provides accurate control of temperature, pressure, gas composition, and flow rates, ensuring reproducible experiments.
* Continuous-Flow Operation: The continuous-flow fixed-bed reactor allows steady-state operation, which is essential for reliable catalytic performance analysis.
* Integration with Analytical Systems: The outlet stream can be directly connected to analytical instruments (e.g., gas chromatography) to monitor product composition and conversion in real time.